Halloween & the Chemist

.

It's Halloween and I thought a little bit about sulphur would be fitting as sulphur is the basis of brimstone and supposedly the smell of Hades is burning brimstone.

I have never seen as pretty a piece of sulphur as that above, apparently it grew in a volcano. Usually, sulphur is a yellow powder. Dull.

Sulphur is the basis of one of the most common food additives, the preservative sulphur dioxide. Which used to be created by burning sulphur.

Still is in Hell, we are told.

Below is a small video on sulphur put out by the University of Nottingham. Like all good chemistry videos, it has explosions in it.




...

Done to a tea.

.

Interesting story about tea recently:

A 44-year-old man presented in May, 2001, with muscle cramps. He had recently switched to drinking Earl Grey tea in preference to his regular black tea.

One week after the change, he noticed repeated muscle cramps for some seconds in his right foot. The longer he drank Earl Grey tea, the more intense the muscle cramps became. After 3 weeks, they also occurred in the left foot...

Earl Grey tea is composed of black tea and the essence of bergamot oil, an extract from the rind of bergamot orange (Citrus aurantium ssp bergamia), which has a pleasant, refreshing scent.

(You can skip this paragraph, if you wish) The adverse effects of bergamot oil in this patient are explained by the effect of bergapten as a largely selective axolemmal potassium channel blocker, reducing potassium permeability at the nodes of Ranvier in a time-dependent manner. This may lead to hyperexcitability of the axonal membrane and phasic alterations of potassium currents, causing fasciculations and muscle cramps.

In other words, it disrupts the way chemicals flow through the membrane of the nerve fibres, causing the neurons that connect to the muscles to malfunction.

I should add he was drinking four litres (a gallon, say) a day.

But it plays into my constant refrain: too much of anything is bad for you.

Food-wise, at least.
...

Hot and cold on Cayenne

medavinci asks "Is it true cayenne pepper can lower blood pressure and open arteries? Can you just sprinkle it on your food or should it be cooked like curry to avoid salmonella? "

OK, a two part question:

Part 1. Is it true cayenne pepper can lower blood pressure and open arteries?

Maybe. Certainly many foods have physiological effects. A peek on the internet finds a squillion and one sites selling the benefits of cayenne pepper (as well as selling the cayenne pepper) but I couldn't find any mainstream sites, just the herbal fringe. This always makes me suspicious. But I have no reason to doubt that it MAY affect blood pressure. In either direction.

Opening arteries is a little more serious. Certainly people can get flushed in the face after eating peppers, chillies and such like. Is the the same as 'opening arteries'? Maybe. Is it desirable to look flushed? Possibly not. Is it the same as unclogging arteries from too many fries over a lifetime? No.

Maybe it works, maybe it doesn't. By the time you find out, the purveyors of fine herbal remedies will be telling you to eat, drink, roll in something else. But, if you feel that it is good for you, then it is. Isn't it?

Do be aware of the possible risks associated with cancers, especially mouth cancers, from excessive and prolonged consumption of irritants like chilli and pepper.

A rule of thumb that I always have with herbal remedies (like the one in this morning's paper that said magnolia flower tea cures hayfever) is a very simple question: if this cure, cayenne pepper, is so good and so effective, why are the major pharmaceutical companies not growing broad-acres of the stuff? These guys are pretty keen to corner the consumer dollar and never slow to see an opportunity.

Could it be that the efficacy of cayenne hasn't been proved to the level of certainty required by good science and the auditors of the Therapeutic Goods Act?

Remember: Alternative medicine that works is called... medicine.

Part 2: Can you just sprinkle it on your food or should it be cooked like curry to avoid salmonella?

If you are consuming it immediately it will be safe to take 'raw' as it were. If you are putting it into something warm, moist and nutritious and not planning to eat it for a few hours, cook it first.

Monosodium Glutamate

.

MSG gets a bad press. Not entirely sure why, as the stories about it are largely unproven.

No uncommonly you will see products claiming 'no MSG'.

Or restaurants with the same sign. No MSG.

They are misleading you folks. What they mean is 'No Added MSG'.

You see, for all its bad press, MSG is naturally occurring in most foods, especially the following:

Meat
Fish
Cheeses, especially hard cheeses like parmesan
Tomatoes and tomato juices, concentrates and sauces
Stocks cubes and concentrates
Sauces such as soy, fish, oyster etc
Spreads such as Vegemite®, Promite®, Marmite® etc.
Foods containing added Hydrolyzed Vegetable Protein (HVP)
Mushrooms
Corn
Peas

And Human breast milk.

Glutamate is produced by the human body and is vital for metabolism and brain function.

Enjoy.
...

French Dressing

.

French dressing is one of the classic salad dressings.

Mine is typically made 'by eye' rather than recipe but, in essence, is as follows:

50ml cider vinegar
200ml olive oil
Crushed garlic, to taste
Qtr teasp mustard powder
Salt & Pepper.

So, for a product that is about 80% oil, how do the Krafts of this world explain the culinary obscenity that is "Fat Free French Dressing"?

Sure, it is a 'salad dressing' but why not call it what it is 'Sweetened, jellied vinegar"?

It's not French. And it's not right.


...

Alcohol & Mouth Cancers.

.

A local news outlet ran with a story recently that said research had shown that increased alcohol consumption lead to increased mouth cancers.

The trail to try to find the supporting research lead back to a UK cancer body but a request for a reference went unanswered.

The report (SBS News) said that over the last 30 years alcohol consumption had gone up and so had the incidence of mouth cancers. Ergo, drinking increases your chances of mouth cancer. The stated increase was 25%.

Sounds scary. But what if the chance had gone from 1 in a million to 1.25 in a million.

Not quite so scary.

And what else has changed over the last 30 years with things that go into people's mouths?

The Western diet has dramatically increased its consumption of chilli, a known mouth irritant.
Much more processed food.
Much more junk food.
Many more novel food additives, such as artificial sweeteners.
Vegetable consumption has decreased.
Fruit consumption has decreased.
Oral sex has, anecdotally, increased. (human papilloma virus (HPV), is a known carcinogen.)
Beer consumption down, wine consumption up.
Genetically modified foods introduced.

To mention just a few.

I will take their survey just a little more seriously when they can tell me how they allowed for these other changes.

And who paid for the research. And why.
...

Nutmeg

.

Most people know of nutmeg, a common spice. Goes well in eggnog and such like.

What most people don't know, and continues my theme that everything is bad for your and laboratory rats at some level, is that nutmeg is toxic. Certainly if you applied to have it approved for use as a new drug you wouldn't get it past the food authorities.

We had a fruitcake submitted due to a complaint that the consumer's lips tingled when she ate the cake. Was it contaminated? No, but it had high levels of nutmeg.

Wikipedia says of nutmeg toxicity:

In low doses, nutmeg produces no noticeable physiological or neurological response.

Large doses can be dangerous (potentially inducing convulsions, palpitations, nausea, eventual dehydration, and generalized body pain).

Users report both negative and positive experiences, involving strong hallucinations, and in some cases quite severe anxiety.

Use of nutmeg as a recreational drug is unpopular due to its unpleasant taste and its possible negative side effects, including dizziness, flushes, dry mouth, accelerated heartbeat, temporary constipation, difficulty in urination, nausea, and panic. In addition, experiences usually last well over 24 hours making recreational use rather impractical.

Good reason to cut back on the nutmeg and up the rum.
...