The red coats came.

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It is hard to believe that these little tackers, small scale insects on a South American cactus, are useful but they are the source of the common food colour, Cochineal.

The very same colour responsible for the original red coats of the British army:



It takes some 70,000 of the little critters to make a pound of dye.

There are two principal forms of cochineal dye: cochineal extract is a colouring made from the raw dried and pulverised bodies of insects, and carmine is a more purified colouring made from the cochineal. To prepare carmine, the powdered insect bodies are boiled in ammonia or a sodium carbonate solution, the insoluble matter is removed by filtering, and alum is added to the clear salt solution of carminic acid to precipitate the red aluminium salt. Purity of colour is ensured by the absence of iron. Stannous chloride, citric acid, borax, or gelatin may be added to regulate the formation of the precipitate. For shades of purple, lime is added to the alum.

-Wikipedia

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Halloween & the Chemist

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It's Halloween and I thought a little bit about sulphur would be fitting as sulphur is the basis of brimstone and supposedly the smell of Hades is burning brimstone.

I have never seen as pretty a piece of sulphur as that above, apparently it grew in a volcano. Usually, sulphur is a yellow powder. Dull.

Sulphur is the basis of one of the most common food additives, the preservative sulphur dioxide. Which used to be created by burning sulphur.

Still is in Hell, we are told.

Below is a small video on sulphur put out by the University of Nottingham. Like all good chemistry videos, it has explosions in it.




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Monosodium Glutamate

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MSG gets a bad press. Not entirely sure why, as the stories about it are largely unproven.

No uncommonly you will see products claiming 'no MSG'.

Or restaurants with the same sign. No MSG.

They are misleading you folks. What they mean is 'No Added MSG'.

You see, for all its bad press, MSG is naturally occurring in most foods, especially the following:

Meat
Fish
Cheeses, especially hard cheeses like parmesan
Tomatoes and tomato juices, concentrates and sauces
Stocks cubes and concentrates
Sauces such as soy, fish, oyster etc
Spreads such as Vegemite®, Promite®, Marmite® etc.
Foods containing added Hydrolyzed Vegetable Protein (HVP)
Mushrooms
Corn
Peas

And Human breast milk.

Glutamate is produced by the human body and is vital for metabolism and brain function.

Enjoy.
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Flavoured e-Cigars

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Chairman Bill said "Instead of smoking, I vape in my e-cigar propylene-glycol with nicotine that has flavourings added - banana, vanilla, etc.

Of late I have been 'cutting' the e-liquid with BP glycerine to make it go further, which does tend to dry out the mucous membranes a tad. However, my question is about added flavourings.

Given the e-liquid is vaporised prior to inhalation, what chemicals that commonly appear in food flavourings should I keep well clear of. I believe caramel bungs up the works of the e-cigar due to the sugars, but I'm led to believe that food flavourings can also have some added chemicals that can undergo a transition when vapourised and could be dangerous.

Blowed if I know, Bill.

It's not that a particular flavouring is dangerous. I am assuming that they are not burnt in the normal cigar/cigarette sense. If that is the case, they are all dangerous.

If the vaporisation is not at a particularly high temperature, they should all be OK.
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Food Additives

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Courtney asked for my “thoughts on food additives in our diet. Specifically, what is your scientific and always logical take on artificial colors/dyes and preservatives in the food and their impact on behavior?”

The answer varies with the additive unfortunately.

Additives fall into a variety of categories but the first major split is into colours and others. Courtney specifically refers to colours, antioxidants and artificial sweeteners.

Colours
Colours are really for cosmetic purposes only and serve no useful purpose to the consumer. They can make pallid and insipid looking foods look more attractive (eg: adding yellow to pasta, cakes or ice-cream makes them look a richer colour, as if they have eggs in them.).

There is no doubt that colours are not necessary. They are an aesthetic additive.

Antioxidants (BHA, BHT, TBHQ)
These additives are generally added to oils and oil containing products to delay the onset of rancidity and extend shelf life; to this end they serve a useful purpose. As well as flavour deterioration, the by-products of rancidity, peroxides and acids, are considered to be harmful. This is where antioxidants have a problem: they are an additive but, unlike colours, they do serve a functional purpose. And this is where the regulators need to walk a fine line: the health risks of the additive vs the health risks of not using the additive.

Artificial Sweeteners
These are more insidious additives, in my mind. There is no denying that obesity is a growing problem (!) but is replacing sugar with something sweet but without calories the answer? It is not training people to enjoy unsweetened food but rather maintaining a need for a certain level of sweetness. Also people do false bargains with the devil when they say “I had a diet cola so I can have a chocolate bar”.

Preservatives
This is a fairly broad group of additives. Sulphur Dioxide is used very widely for different reasons. With the likes of sausages, they will not last a day raw without preservative (because you are seeding the minced raw meat with bacteria filled other components – flours, spices etc.). Dried fruit, such as apricots, go dark brown without preservative but will survive quite well without it IF they are properly dried. If they are kept still moist, (could they be being sold by weight?) yeasts can grow in them. Many soft drinks contain the preservative Benzoic Acid to prevent the growth of bacteria during storage. Again there is the issue of the health risks of using the additive vs the health risks of not using the additive.

At one level, it seems logical that manufacturers will not use additives unless they feel that they are needed in their food. Why incur an unnecessary cost? But reality is that the cost of the additive is not great and the ability of the manufacturers to control the amounts added is variable. Ultimately, as an insurance, they often use too muych rather than too little.

That was the easy bit.

“Are these additives harmful?” is a harder question. At some point everything is harmful. One grain of sand will bounce off you shoulder, a truck full dumped on you will smother you. Do additives impact on children’s behaviour? Quite possibly. There is the issue of causality though. This is something that I will probably come back to time and time again in this blog. Do colours make your child hyperactive? Or is it the sugars that are often present with the colours? Or something else altogether?

Ultimately it is something that must be decided on a case by case basis. If they affect your child, all the assurances of the ‘experts’ amount to nothing; they affect your child.
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