The criminal mind

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There was a newspaper item this morning about police in the US finding a body. It was disfigured and minus fingers and teeth, to avert identification.

But first a diversion...

I used to work at the coroner's court labs in Melbourne. People would drown someone in a bath tub and then throw them into the sea, not realising that we looked at the water in their lungs to see if they drowned at sea. They would kill someone and then burn the house down, not realising that we looked at the blood for evidence of the carbon monoxide poisoning that would be present in a fire victim and absent if they where dead before the fire started.

I used to work looking at foreign matter in food. We could often tell if the object was in there before cooking or entered after, either by accident, sabotage or extortion. Insects, for example, have an enzyme called phosphatase which is destroyed by cooking. If you must slip a cockroach into a pizza, cook it first.

Time and time again, people wanting to commit a crime, big or small, overlook something quite basic.

Back to our anonymous lady...

The police identified her by the serial numbers on her breast implants.
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Radioactive Calamari

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Every so often we get stories that go along the lines of :

"I went out to the kitchen in the middle of the night to get a glass of water. I didn't turn the light on and I saw the food in the cat bowl was glowing!

Is it radioactive?"

Most spectacular when it is calamari rings.

No, it is not radioactive, it is just active. With bacteria.

Pseudomonas fluorescens. A common spoilage bacteria that secretes a fluorescent pigment. It is generally harmless to humans unless they are already immunocompromised.
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A little more on garlic...

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While we are on the topic of garlic, I was presented with a complaint once where the lady had mixed chopped garlic with lemon juice and microwaved it.

It turned bright green.

Some months later I was shown a bottle of garlic cloves, preserved in vinegar, that had similarly gone bright green.

What's going on?

Part of the problem is that this is not how garlic was traditionally treated. It would normally be cooked in a neutral sauce. And a thick sauce that hid it from view.

The two complainants were treating garlic in a a totally different way to normal.

But the reactions were perfectly normal.

Garlic has natural levels of iron and natural levels of sulphur compounds. Heated in the presence of an acid (lemon juice or vinegar) these compounds react to form iron sulphide which shows as a green colour.

Harmless.
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Of vampires and garlic.

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"Vampires are feared everywhere, but the Balkan region has been especially haunted. Garlic has been regarded as an effective prophylactic against vampires.

We wanted to explore this alleged effect experimentally.

Owing to the lack of vampires, we used leeches instead. In strictly standardized research surroundings, the leeches were to attach themselves to either a hand smeared with garlic or to a clean hand. The garlic-smeared hand was preferred in two out of three cases (95% confidence interval 50.4% to 80.4%). When they preferred the garlic the leeches used only 14.9 seconds to attach themselves, compared with 44.9 seconds when going to the non-garlic hand (p < 0.05).

The traditional belief that garlic has prophylactic properties is probably wrong. The reverse may in fact be true.

This study indicates that garlic possibly attracts vampires."

Tidsskr Nor Largeforen. 1994 Dec 10;114(30):3583-6.

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A troublesome crystal

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A while ago we were talking about kidney stones. One of the variety of things that kidney stones can be comprised of is Struvite. To the chemically inclined, it is ammonium magnesium phosphate.

But today I want to mention one of struvite's other incarnations.

Tinned fish.

Struvite crystals will grow in tinned fish, especially salmon. Looking for all the world like pieces of windscreen glass after a crash, the crystals will come in for testing as "glass found in a tin of fish".

But it is not glass. And it is not harmful.

Should you swallow some it will dissolve in your gastric juices.
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Flavoured e-Cigars

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Chairman Bill said "Instead of smoking, I vape in my e-cigar propylene-glycol with nicotine that has flavourings added - banana, vanilla, etc.

Of late I have been 'cutting' the e-liquid with BP glycerine to make it go further, which does tend to dry out the mucous membranes a tad. However, my question is about added flavourings.

Given the e-liquid is vaporised prior to inhalation, what chemicals that commonly appear in food flavourings should I keep well clear of. I believe caramel bungs up the works of the e-cigar due to the sugars, but I'm led to believe that food flavourings can also have some added chemicals that can undergo a transition when vapourised and could be dangerous.

Blowed if I know, Bill.

It's not that a particular flavouring is dangerous. I am assuming that they are not burnt in the normal cigar/cigarette sense. If that is the case, they are all dangerous.

If the vaporisation is not at a particularly high temperature, they should all be OK.
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Kidney Stones

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Kidney stone crystals.

Kris Loves Chocolate asks: "Could there be any truth to drinking pickle juice to dissolve a kidney stone? "

First let me say that I am a food chemist, not a pharmacist. By rights, I have no right to answer medical questions and any answer is based more on logic than medical knowledge.

Now, having said that, let me say this:

Kidney stones are things that have deposited, crystallised, from your urine. There are several types of kidney stones, so no one thing will cure them all.

For something like pickle juice, basically vinegar, to dissolve them it would need to get past your stomach and intestinal system and have an influence on the composition of your urine. Not impossible, by all accounts something in cranberries makes the passage and has a remedial effect with regard to urinary tract infections. But I am not convinced that acetic acid, the acid in pickle juice, will do that. Most body fluids are pretty tightly controlled for their pH.

More plausible is that drinking more fluids may lower the concentration of the salts in the urine that lead to the stones and then they may redissolve.

May.

I see no reason why pickle juice cannot be this fluid but water would be more palatable.

For more informed information, visit the Mayo Clinic site.
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